A 2D azine-linked covalent organic framework for gas storage applications.
نویسندگان
چکیده
A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g(-1) of CO2, 9.9 mg g(-1) of H2, and 11.5 mg g(-1) of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 50 89 شماره
صفحات -
تاریخ انتشار 2014